Enthalpy Relaxation Phenomenon in a Heavy Ice Crystal

Anomalous Enthalpy Relaxation in Vitreous Silica

It is a challenge to calorimetrically determine the glass transition temperature (Tg) of vitreous silica. Here, we demonstrate that this challenge mainly arises from the extremely high sensitivity of the Tg to the hydroxyl content, but also from decrease of the Tg with repeating the calorimetric scans. It is known that the liquid fragility (i.e., the speed of the viscous slow-down of a supercoo...

A Thickness and Enthalpy Distribution Sea-Ice Model

The theory of sea ice thickness distribution developed by Thorndike et al. has been extended to include sea ice enthalpy distribution. The extended theory conserves both ice mass and thermal energy, in the form of the heat stored in the ice, by jointly solving a thickness-distribution equation and an enthalpy-distribution equation. Both equations have been implemented in a one-dimensional dynam...

enthalpy relaxation of gelatin in the glassy state

the glass transition temperature (tg) and the melting temperature (tm) of gelatin at water contents between 7 and 14% were measured using differential scanning calorimetry.  the plasticisation of the polymer by water led to a decrease in tg and tm. the tg of partially crystalline gelatin was higher than that of the amorphous one obtained by quenching from the melt. the enthalpy relaxation occur...

The adsorption enthalpy of nitrogen oxides on crystalline ice

The partitioning of nitrogen oxides between ice and air is important to the ozone budget in the upper troposphere. In the present study, the adsorption of nitrogen oxides on ice was investigated at atmospheric pressure using a chromatographic technique with low concentrations of radioactively labelled nitrogen oxides. The measured retentions solely depended on molecular adsorption and were not ...

Thermodynamics of Enthalpy Relaxation and Hole Formation of Polymer Glasses